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pyrethroids Pyrethroids, synthetic versions of natural compounds found in
flowers, are used extensively in
pesticides .
Pyrethroids have been considered safer than
DDT and
chlordane because they
did not seem to build up in the environment.
Pyrethroids are the second
most common class of pesticide that results in poisoning. In high doses,
pyrethroids are toxic to the nervous
system.
At low doses, they alter hormones. The pyrethroid compounds
are used in large volumes in farm and household pesticides and are sprayed by
public agencies to kill mosquitoes.
phenothiazine
Long term use of neuroleptics is linked to visible
shrinkage of the frontal lobes - the part of the brain used for higher level
thought.1876
An aniline dye methylene blue, a derivative of
phenothiazine, is synthesized by Heinrich Caro at
BASF.
1883
Heinrich August Bernthsen synthesized phenothiazine
S(C6H4)2NH.
mid
1880s Paul Ehrlich began to use methylene blue in his cell staining
experiments that led to pioneering discoveries about different cell
types.
1890s Methylene blue is being used to
treat malaria.
1935
DuPont introduced the chemical
phenothiazine as an insecticide.
The term "phenothiazines" describes the
largest of the five main classes of neuroleptic antiPsychotic chemicals.
It is claimed these chemicals have
antiPsychotic and antiemetic
properties.
Phenothiazine may cause severe
side effects such as akathisia (inability to remain motionless),
tardive dyskinesia (involuntary
repetitive movements) as well as other extrapyramidal symptoms such as an
inability to move, and the rare but potentially fatal neuroleptic
malignant syndrome as well as substantial weight gain.
Tardive dyskinesia
appears to be related to damage to the part of the nervous system that uses and
processes the neurotransmitter
dopamine.
Targeting the receptor CB2 in a mouse model of l-dopa
induced dyskinesia
Phenothiazine
antiPsychotics are
classified into three groups that differ with respect to the substituent on
nitrogen:
the aliphatic compounds (bearing acyclic groups);
the
"piperidines" (bearing piperidine-derived groups);
and the piperazine
(bearing piperazine-derived substituents).
Aliphatic
compounds
Chlorpromazine marketed as
Thorazine®, Chlor-PZ®,
Klorazine®, Promachlor®, Promapar®, Sonazine®, Chlorprom®,
Chlor-Promanyl®, Largactil®.
Promazine marketed as
Sparine®
Triflupromazine marketed as Stelazine®, Clinazine®,
Novaflurazine®, Pentazine®, Terfluzine®, Triflurin®,
Vesprin®
Levomepromazine/Methotrimeprazine marketed as Nozinan®,
Levoprome®
Piperidines
Mesoridazine
marketed as Serentil®
Thioridazine marketed as Mellaril®,
Novoridazine®, Thioril®
Piperazines
Fluphenazine marketed as Prolixin®, Permitil®,
Modecate®, Moditen®
Perphenazine marketed as Trilafon®,
Etrafon®, Triavil®, Phenazine®
Flupentixol marketed as
Depixol®, Fluanxol®
Prochlorperazine marketed as
Compazine®, Stemetil®®
Trifluoperazine marketed as
Stelazine®
Most phenothiazines act as
strong central nervous
system sedatives.
Examples of phenothiazine antiPsychotics are:
prochlorperazine (Compazine®, Compro®, Procomp®), chlorpromazine
(Promapar®, Thorazine®), fluphenazine (Permitil®, Prolixin®),
perphenazine, trifluoperazine (Stelazine®), thioridazine (Mellaril®)
and mesoridazine (no longer available in the United States).
Long term use of
neuroleptics shows visible shrinkage of the frontal lobes -
the part of the brain
used for rational thought, the same part targeted by
the frontal
lobotomy and electroshock
treatments.
1944 3,500,000 pounds of
phenothiazine is sold in the US.
Phenothiazine use declines after 1944
as it quickly degrades in sunlight and air, so it is difficult to determine how
much to use in the field.
Phenothiazine is largely replaced by DDT which
is more durable |
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